XPS Analysis of the PC/PVDF interface modified by PMMA. Location of the PMMA at the interface

Moussaif, N., Pagnoulle, C., Riga, J. and Jérôme, R. XPS Analysis of the PC/PVDF interface modified by PMMA. Location of the PMMA at the interface. Polymer. 2000, Vol. 41, p. 3391-2000.

<p>Polycarbonate (PC) and polyvinylidenefluoride (PVDF) are two immiscible polymers, which form two-phase polyblends with a weak interfacial adhesion and a high interfacial tension. This situation may be changed by the addition of polymethylmethacrylate (PMMA), which is miscible with PVDF and concentrates at the PVDF/PC interface. Location of PMMAat the PC/PVDF interface has been confirmed by XPS analysis, which shows that the interface enrichment in PMMA already takes place when only 10 wt% PMMA is premixed with PVDF. @2000 Elsevier Science Ltd. All rights reserved. Keywords: Polycarbonate; Polyvinylidenefluoride; Polymethylmethacrylate</p>